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4-Methylumbelliferyl-beta-D-glucopyranoside

  • CAS No.: 18997-57-4
  • Purity: 99%
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Good factory supply good 4-Methylumbelliferyl-beta-D-glucopyranoside 18997-57-4

  • Molecular Formula: C16H18 O8
  • Molecular Weight: 338.314
  • Appearance/Colour: White Powder 
  • Melting Point: 258-263 °C (dec.) 
  • Refractive Index: 1.4430 (estimate) 
  • Boiling Point: 626.9 °C at 760 mmHg 
  • PKA: 12.73±0.70(Predicted) 
  • Flash Point: 233.9 °C 
  • PSA: 129.59000 
  • Density: 1.522 g/cm3 
  • LogP: -0.71990 

18997-57-4 Relevant articles

OleD Loki as a Catalyst for Tertiary Amine and Hydroxamate Glycosylation

Hughes, Ryan R.,Shaaban, Khaled A.,Zhang, Jianjun,Cao, Hongnan,Phillips, George N.,Thorson, Jon S.

, p. 363 - 367 (2017)

We describe the ability of an engineered...

Glycyrrhetinic acid exhibits strong inhibitory effects towards UDP-glucuronosyltransferase (UGT) 1A3 and 2B7

Huang, Yin-Peng,Cao, Yun-Feng,Fang, Zhong-Ze,Zhang, Yan-Yan,Hu, Cui-Min,Sun, Xiao-Yu,Yu, Zhen-Wen,Zhu, Xu,Hong, Mo,Yang, Lu,Sun, Hong-Zhi

, p. 1358 - 1361 (2013)

The aim of the present study is to evalu...

The Novel UDP Glycosyltransferase 3A2: Cloning, catalytic properties, and tissue distribution

MacKenzie, Peter I.,Rogers, Anne,Elliot, David J.,Chau, Nuy,Hulin, Julie-Ann,Miners, John O.,Meech, Robyn

, p. 472 - 478 (2011)

The human UDP glycosyltransferase (UGT) ...

Molecular cloning and biochemical characterization of a new coumarin glycosyltransferase CtUGT1 from Cistanche tubulosa

Xu, Xiping,Yan, Yaru,Huang, Wenqian,Mo, Ting,Wang, Xiaohui,Wang, Juan,Li, Jun,Shi, Shepo,Liu, Xiao,Tu, Pengfei

, (2021)

UDP-glycosyltransferases (UGTs) are an i...

Solvent-Dependent Mechanism and Stereochemistry of Mitsunobu Glycosylation with Unprotected Pyranoses

Fujimori, Yusuke,Furuta, Takumi,Kawabata, Takeo,Nagaishi, Masaru,Sasamori, Takahiro,Shibayama, Hiromitsu,Takeuchi, Hironori,Tokitoh, Norihiro,Ueda, Yoshihiro,Yoshimura, Tomoyuki

supporting information, (2020/06/29)

An SN2 mechanism was proposed for highly...

Based on 4 - methyl [...] synthesis method of a plurality of glycoside

-

Paragraph 0080; 0081, (2018/10/11)

The invention discloses a method for syn...

Glucosyltransferase Capable of Catalyzing the Last Step in Neoandrographolide Biosynthesis

Li, Yuan,Lin, Hui-Xin,Wang, Jian,Yang, Jian,Lai, Chang-Jiang-Sheng,Wang, Xing,Ma, Bao-Wei,Tang, Jin-Fu,Li, Yong,Li, Xin-Lin,Guo, Juan,Gao, Wei,Huang, Lu-Qi

supporting information, p. 5999 - 6002 (2018/10/20)

ApUGT, a diterpene glycosyltransferase f...

18997-57-4 Process route

4′-methylumbelliferyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside
67909-25-5

4′-methylumbelliferyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

4-methylumbelliferyl β-D-glucopyranoside
18997-57-4,39940-54-0

4-methylumbelliferyl β-D-glucopyranoside

Conditions
Conditions Yield
With potassium hydroxide; In methanol; at 20 ℃; for 1h;
83%
With methanol; potassium hydroxide; at 20 ℃; for 1h;
83%
With methanol; sodium methylate; at 20 ℃; for 0.5h;
55%
With methanol; barium methoxide;
With methanol; sodium methylate;
With sodium hydroxide;
With sodium methylate; for 5h; Yield given; Ambient temperature;
With sodium methylate; In methanol; at 20 ℃; for 1h; Inert atmosphere;
74.3 mg
alpha-D-glucopyranose
492-62-6

alpha-D-glucopyranose

7-hydroxy-4-methyl-chromen-2-one
90-33-5,79566-13-5

7-hydroxy-4-methyl-chromen-2-one

4-methylumbelliferyl β-D-glucopyranoside
18997-57-4,39940-54-0

4-methylumbelliferyl β-D-glucopyranoside

Conditions
Conditions Yield
With di-isopropyl azodicarboxylate; triphenylphosphine; In 1,4-dioxane; at 55 ℃; for 1h; stereoselective reaction; Inert atmosphere;
82%

18997-57-4 Upstream products

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18997-57-4 Downstream products

  • 6160-80-1
    6160-80-1

    4-methylumbelliferyl-β-D-glucuronide

  • 90-33-5
    90-33-5

    7-hydroxy-4-methyl-chromen-2-one

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    50-99-7

    D-glucose

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    4-methylumbelliferyl 4,6-O-benzylidene-β-D-glucopyranoside

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